2.3. Engineering materials¶
Syllabus Excerpt
testing of materials
hardness
impact
heat treatment of ferrous metals
annealing
normalising
hardening and tempering
changes in macrostructure and microstructure
changes in properties
manufacturing processes for ferrous metals
forging
rolling
casting
extrusion
powder forming
welding
changes in macrostructure and microstructure of ferrous metals
changes in properties of ferrous metals
manufacturing processes for non-ferrous metals
alloying
annealing
solid solution hardening
changes in macrostructure and microstructure of non-ferrous metals
changes in properties of non-ferrous metals
ceramics and glasses
as an insulation material
laminating and heat treatment of glass
structure/property relationship and their application
thermo softening polymers
engineering textiles
manufacturing processes
extrusion
injection moulding
blow moulding
structure/property relationships and application
2.3.1. Testing of Materials¶
2.3.2. Heat Treatment of Ferrous Metals¶
2.3.3. Manufacturing Processes for Ferrous Metals¶
Forging¶
Where metal is deformed due to compressive or high impact forces
Forged objects are stronger than machined objects as it creates grainflow
Functions that can be performed by forging are:
Upsetting
Flattening the metal
Increases cross-sectional area by reduces length
Drawing
Metal drawn out by hammering along sides
Increases length by reducing cross-sectional area
Hot Forging¶
The metal is heated to above recrystallisation temperature and then worked at the temperature
After working it is left to cool
Much easier to change the shape of the metal as it becomes malleable
(heating) will relieve internal stresses, increasing toughness and durability but decreases the hardness
prevents strain hardening
FCC not BCC is formed
due to heating, the material can warp due to thermal contraction/expansion -> low dimensional accuracy and poor surface finish
Cold Forging¶
Large amounts of force are applied to the metal at (mostly) room temperature
usually for softer metals
retains dimensional acccuracy and surface finish
However, creates residual stresses which leads to lower ductility and toughness, but harder
Can often be accompanied by later annealing to relieve stresses
Rolling¶
Metal is passed through a set of rolls, which exert a compressive force on the sheet. This creates a reduction thickness an extension in length.
Hot Rolling¶
Done at temperatures above recrystallisation
Produces fine, equiaxed, and unstressed grains
Requires less force
Not dimensionally accurate or good surface finish
Can form an oxide layer
Cold Rolling¶
Produces elongated and stressed grains
Harder and stronger final product
Better surface finish
Less ductile
Elongated grains -> only strong in two dimensions
Requires high amounts of form
Casting¶
A general category involving pouring molten metal into a mould. Most of the difference comes in how the mould is made.
The solidification of pure metals has a defined temperature at which the metal transitions from liquid to solid. This causes a solidification front to move through the material, from the outer walls into the centre. Non-pure metals have a range of temperatures where the metal solidifies, this is the ‘mushy’ region.
At the mould walls, the metal cools rapidly and creates an outer shell of equiaxed grains. Grains will then grow opposite direction of heat transfer, forming columnar grains inwards on the material. Further away from the walls, the grains grow slower and are able to become equiaxed and course. The addition of nucleating agents (see (c)) creates course grains throughout. In alloys, dendrites form of the material with a higher freezing point.
Slower cooling creates coarser structures, and faster cooling creates finer dendritic structures.
Smaller grain size increases strength and ductility. Lack of uniform grain structures create anisotropic properties (not uniform in all directions).
Convection within the metal promotes the formation of the outer chill zone and the transition from columnar to equiaxed grains. Reducing convection creates more columnar structures.
Sand Casting¶
A pattern (made from wood or other material) is made from a design by a skilled pattern maker; in two parts, the cope and the drag [top and bottom] and mounted on plates
The cope pattern is placed within a flask, alongside a pattern for a sprue (for adding metal) and riser. It is then filled with sand that is then rammed to compact it.
This is repeated with the drag, except there is no sprue or riser.
The patterns are then removed.
The cope and drag are assembled together.
Metal is then poured into the sprue via the pouring basin
The pouring basin is used to ensure consistent flow of metal
The metal is then allowed to cool and then the cope and drag are separated. The excess parts created by the runner and riser are then machined off.
The sand can then be reused
Advantages of sand casting:
Cost effective
Relatively simple to do
Suitable for small or large production runs
Disadvantages:
Poor surface finish -> fatigue cracking
Poor dimensional tolerance and stability
Grains are often columnar
Properties become anisotropic
Large grains reduce ductility
Weakness where columnar grains meet equiaxed grains
Resolved with the addition of innoculants, which encourage nucleation (formulation of new crystals)
Shell Moulding¶
A metal (usually cast iron) pattern is made by hand and is then heated to ~200-300C
Fine silica sand combined with ~5% thermosetting phenotic resin is then dumped onto the metal pattern, and left to cure for a few minutes.
The pattern + sand are then inverted, allowign the excess (non-cured) sand to drop free. This leaves a 10-20mm shell.
The pattern + sand are then placed in an oven to finish curing.
The shell is then removed from the pattern via a removing pin, and combined with #. the other half of the shell by clamping/gluing/adhsive, forming a mold.
The shell is then placed in a flask filled with shot or sand.
Metal can then be poured into the shell and left to set.
The shell is then removed and discarded.
Advantages:
can be completely automated
law labour cost
efficient
very good surface finish and dimensional tolerance
relatively short lead time (~weeks)
large and complex parts can be produce (similar to sand casting)
Disadvantages:
the initial cast iron pattern is moderately expensive to make and hence requires long runs to be economical
the dumping / shell moulding machine is expensive
can be highly porous
part size limited
Permanent Metal Mould / Gravity Die Casting¶
A die is made from steel. This is very expensive and can take a while to make. It integrates the sprue and riser as part of the mould.
The die must be able to be separated along one plane
Metal can be poured into the mould, left to cool, then the mould is pulled apart
Advantages:
good dimensional accuracy and surface finish
high production rate
Disadvantages:
high die cost
limited part size
long lead time
limited to nonferrous metals e.g. aluminium as the melting point needs to be lower than that of the die itself
Pressure Die Casting¶
Similar to gravity die casting but is done under high pressure.
Advantages:
excellent dimensional acuracy and surface finish (pressure forces into surface)
high production rate
Disadvantages:
lead time of up to a few months
very expensive die cost
Lost Foam Casting¶
A pattern is made from polystyrene by heating polystyrene beats containing pentane inside of an aluminium die, which is then separated
The polystyrene foam is then placed in a box with fine sand which is then compacted.
Molten metal is poured in and vapourises the foam pattern.
Advantages:
simple process as no parting lines, risers, or cores
minimal cleaning and finishing operations necessary
Disadvantages:
die cost is expensive
metal cools faster as energy is taken out through vapourisation of foam * formation of more columnar structures rather than equiaxed
patterns low strength
Investment Casting¶
A pattern is created of wax through moulding or other techniques
The wax patterns are often joined together in large trees, then covered in a fine silica and binders
Once dried, it is then repeatedly coated in more sand to increase the strength of the mould
The mould is then heated (~150C) to melt out the wax
It is then fired at 600-1000C to burn out any remaining wax or chemicals
Molten metal is then poured into the mould and then the mould is broken up to reveal castings
Can be used for manufacture of orthopedic replacements e.g. the knee. Suitable for use with titanium, chrome, or cobalt alloys.
Advantages:
excellent surface finish and dimensional accuracy
very high production rates
can cast high melting point alloys
removes the need for most finishing or machining processes, which can reduce cost
creates equiaxed grains through the mould, leading to better properties
thin walls (1.5mm) can be created
Disadvantages:
expensive tooling cost, lead time of a few weeks * creation of both wax mould and then this secondary mould
part size limited (up to ~35kg)